This paper considers the manufacturing issues associated with dimethyl formamide, γ-butyrolactone, dimethyl sulfoxide and chlorobenzene solvents, in particular the health and safety issues of using these solvents in scaled perovskite photovoltaic processing. Issues of device lifetime are also considered, for example the effects of atmospheric conditions (e.g. humidity).
We report a solvent-free approach to synthesizing organolead perovskites by using solid state reactions to coat perovskite crystals onto Al2O3 or TiO2 nanoparticles followed by addition of terpineol affording perovskite inks. We have bar cast these inks to produce photoactive perovskite thin films which are significantly more stable to humidity than solution-processed films. This new method also avoids the use of toxic DMF solvent.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.