Biodegradable polymer nanocomposites of poly(lactic acid) (PLA) and several organically modified montmorillonites (nanoclays), namely, Cloisite 30B, Cloisite Na + , Cloisite 25A, Cloisite 20A, Cloisite 93A, and Cloisite 15A were prepared by melt compounding using a Brabender twin-screw extruder. An exfoliated morphology was observed using both X-ray diffraction analysis (XRD) and transmission electron microscopy (TEM) for the combination of PLA and Cloisite 30B (the montmorillonite modified with a quaternary ammonium salt). The first XRD peaks for all the other nanocomposites were observed to shift to lower angles, indicating that intercalation occurred. The extent of intercalation depended on the type of organic modification on the Cloisite organoclay and was exhibited in the sequence of Cloisite Na + > 25A > 20A > 93A > 15A. Further studies were carried out to compare the properties of the PLA-30B nanocomposites with those of the neat PLA at clay loading levels of 1%, 2%, 3%, 4%, and 5% (w/w). Thermal stability of the nanocomposites was studied using thermogravimetric analysis (TGA). An increase in thermal stability was observed with a high at a loading level of 3% (w/w). Biodegradable Poly(Lactic Acid)/Clay Nanocomposites 337Glass transition data were collected and analyzed using differential scanning calorimeter (DSC). An optimum in the glass transition temperature T g of the nanocomposites was observed at 3% (w/w). Improvement in the mechanical properties of the nanocomposites was also observed.

No abstract

No abstract

No abstract

This paper discusses a proof test procedure for estimating and extending the fatigue life of composite coupons. The estimates were based on the acoustic emission data collected during the described proof test procedure. A group of coupon specimens that included both undamaged as well as damaged ones were tested to verify the ability to estimate the fatigue durability. For majority of the specimens tested the fatigue life of the coupons is inversely proportional to the cumulative AE energy collected during the proof test procedure. Based on the trend that was established, a new group of specimens AE based proof test was performed and using the acoustic emission response, the life was estimated. If one could estimate the fatigue life, it would be possible to identify those specimens, which are likely to fail prematurely. For such specimens it may be possible to extend the fatigue life by appropriate reduction in the cyclic load amplitude. This hypothesis was tested on the last group of specimens. The results obtained during the life extension phase actually show that it is possible to identify the specimens, which are likely to have short life and extend the fatigue life by subjecting them to less demanding load history.