We observed the growth of unusual Mg nanoblades by oblique angle deposition. Although the vapor flux is obliquely incident, these nanoblades stand vertically on the substrates. The thickness of the Mg nanoblades along the incident vapor direction is reduced to approximately 15 nm to -30 nm at a vapor incident angle approximately 75 degrees, while the width perpendicular to the incident vapor direction is as wide as a few hundred nm. In addition to the anisotropic blade morphology, a (1010) [0001] biaxial (II-O) texture was observed using in situ reflection high energy electron diffraction (RHEED). The tilt angles of the texture axis and the nanoblades are correlated with the high surface diffusion on the (0001) surface along the [2130] direction. We also propose that the observed very thin thickness of the nanoblade along the vapor flux direction is due to the appearance of the surface steps parallel to the [0110] direction and the low surface diffusion on the top surface of the nanoblades.
We present hydrogenation/de-hydrogenation properties of ultrathin Mg nanoblades coated with Pd as a catalyst. The hydrided Pd/Mg/Pd and Pd/Mg nanoblades were highly curved as observed by ex situ scanning electron microscopy. An in situ thermal desorption spectroscopy (TDS) study showed that the hydrided Pd/Mg/Pd nanostructure has a low hydrogen desorption temperature, at ∼365 K. Through a combinational microstructure and TDS analysis of hydrided Pd/Mg/Pd nanoblades as well as hydrided Pd/Mg/Pd nanoblades covered with an additional ultrathin Mg layer, we found that the effect of Pd catalyst on reducing the hydrogen desorption temperature is significantly stronger than the conventionally proposed mechanisms due to grain size and strain.
We report the creation of unusual biaxial textures in Cu nanorod films, through the control of the incident vapor flux during oblique angle deposition. High-density twin boundaries were formed using a periodic azimuthal swing rotation of the substrate while the incident angle of the Cu flux was fixed at 85° with respect to the surface normal. In contrast, depositions on stationary substrates resulted in nanorod films with a much lower density of twinned crystals. From transmission electron microscopy and x-ray pole figure analysis, the nanorod axis was shown to coincide approximately with the [Formula: see text] crystallographic directions. We also observed the branching of these nanostructures into 'nanotrees'. This branching was attributed to the creation of edge dislocations during the deposition and was particularly prevalent for the case of swing rotation. The mechanisms for the development of texture, twinning, and branching in these nanostructures are discussed.
In a single-centre, randomized trial, gasless laparoscopic myomectomy was compared with conventional laparoscopic myomectomy. The study examined feasibility, safety, reliability and post-operative outcomes. Estimated blood loss, duration of surgery, early post-operative outcomes and length of hospital stay were recorded. Compared with conventional laparoscopic myomectomy, gasless laparoscopy resulted in significantly lower intra-operative blood loss (median 100 ml vs 80 ml, respectively) and duration of surgery (median 94 min vs 71 min, respectively). Post-operative abdominal drainage volume was significantly lower after gasless laparoscopy than after conventional laparoscopy (median 100 ml vs 240 ml). There was no significant difference between duration of post-operative fever, post-operative time to flatus or length of hospital stay. Both forms of laparoscopy are suitable for uterine myomectomy, and comparison of these methods showed that gasless laparoscopy had potential advantages over conventional laparoscopy.
ABSTRACT. Partial duplication of the long arm of chromosome 11 and the partial trisomy of 22q are uncommon karyotypic abnormalities. Here, we report the case of a 6-year-old girl who showed partial trisomy of 11q and 22q, as a result of a maternal balanced reciprocal translocation (11;22), and exhibited dysmorphic features, severe intellectual disability, brain malformations, and speech delay related to this unique chromosomal abnormality. Array comparative genomic hybridization (array CGH) revealed a gain in copy number on the long arm of chromosome 11, spanning at least 18.22 Mb. Additionally, there was a gain in copy number on the long arm of chromosome 22, spanning at least 3.46 Mb. FISH analysis using a chromosome 11 short arm telomere probe (11p14.2), a chromosome 11 long arm telomere probe (11q24.3), and a chromosome 22 long arm telomere probe (22q13.33) confirmed the origin of the marker chromosome. It has been confirmed by the State Key Laboratory of Medical Genetics of China that this is the first reported instance of the karyotype 47,XX, +der (22
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