TMAP-TEMPO represents an extremely stable redox-active radical organic for an AORFB posolyte. An all-organic AORFB based on TMAP-TEMPO and BTMAP-Vi exhibits an OCV of 1.1 V and a long lifetime, featuring a concentrationindependent temporal capacity retention rate of >99.974% per h, or a capacity retention rate of 99.993% per cycle over 1,000 consecutive cycles.
Due to the promising applications in low-cost and high performance photovoltaic and thermoelectric devices, there has been a booming development of syntheses of colloidal I-III-VI 2 and I 2 -II-IV-VI 4 (I ¼
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