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The mechanochemical interconversion of two salts was achieved by the addition of an appropriate amount of one of the corresponding components (HL or CuCl2·2H2O), and the progress of dynamic interconversion was revealed by PXRD, fluorescence and Raman spectroscopy.

The solid-state reactivity among nonporous Cu(ii) second and first sphere adducts has been studied using a multidentate flexible ligand in combination with quantum mechanics.

Controlled synthesis of a series of metal–organic salts and coordination complexes is tuned by the protonation of ligand, and their transformations are induced by the solid–gas and concentration of [H+].