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A novel superabsorbent polymer composite was synthesized by graft copolymerization of cottonseed protein and acrylic monomers in order to explore the new application of cottonseed protein in nonfood field. This composite was synthesized by solution based copolymerization, using partly neutralized acrylic acid, acrylamide and cottonseed protein as raw material, N,N‐methylene bisacrylamide as crosslinking agent, potassium persulphate and sodium sulfite as the initiators. The effects of the certain variables of the copolymerization on the water absorbency of the synthesized composite were measured. The chemical structure of the composite was characterized by means of Fourier transform infrared spectroscopy, differential scanning calorimetry and thermogravimetry analysis. The swelling properties of the composite were carried out under varying pH conditions. Further, the saline sensitivity, swelling kinetics and water retention ability of the composite was investigated. POLYM. COMPOS., 2011. © 2011 Society of Plastics Engineers

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This work examines the interfacial structure and interaction between water and polymer chains in the hydrogel-hydrogel composites with the goal of establishing foundations for further investigation of drug diffusion from one hydrogel to another in the soft contact lens. This is based on the ability of the hydrogel-hydrogel composites to release ophthalmic drugs in a sustained manner. The hydrogel-hydrogel composites were synthesized by immersing the glycerol-swollen particles of crosslinked N-vinyl-2-pyrrolidone (NVP) into the monomer of hydroxyethylmethacrylate (HEMA) containing initiator benzoylperoxide (BPO) that polymerizes to form a matrix in the presence of the first networks. The hydrogel-hydrogel composites were characterized by UV/Vis spectrophotometer, scanning electronic micrography (SEM), and differential scanning calorimetry (DSC). The results showed that the samples of hydrogelhydrogel composites of the particles of crosslinked NVP and poly-HEMA were transparent and glassy and suitable for soft contact lens. Three types of the interfacial structure, no interpenetrating interface, partly interpenetrating interface, and fully interpenetrating interface, of the hydrogel-hydrogel composites existed, and the type of the interfacial structure was determined by the degree to which the monomer of HEMA penetrated into the first networks before formation of the matrix. Different from poly-HEMA hydrogels, the peaks near 08C on DSC curves of the hydrogel-hydrogel composites did not split while they were kept acute, and the amount of freezable-bound water was less. This shows that the water incorporated in the hydrogel-hydrogel composites does not strongly interact with polymer matrix, so the hydrogel-hydrogel composites cannot keep their shape during the phase transition of water.