No abstract

Composite mineral-biochars of a homogeneous biomass (cellulose) and heterogeneous biomass (oak leaves) were fabricated with either 5wt% or 10wt% minerals (montmorillonite (MMT), kaolinite, and sand), and then pyrolyzed at 600 °C for 60 min. Characterizations including proximate analysis, ultimate analysis, surface area and porosity, morphology and surface chemistry confirmed that minerals were present on the surface of biochar, and MMT/kaolinite-biochar composites showed a strengthening in the chars’ aromatic structures, as well as increases in oxygen-containing surface functional groups. Methylene blue adsorption isotherms indicated that the MMT/kaolinite-biochars had higher adsorption capacities than pure biomass or biomass-sand biochars (110 mgMB/gchar and 24 mgMB/gchar for MMT-cellulose char and cellulose char, respectively). A multilinear model relating adsorption capacity and adsorbent properties was developed to measure the relative contribution of biochar properties to adsorption behavior. The model indicates that pore volume and hydrogen bonding were the dominant properties in controlling the adsorption of methylene blue onto the biochars. Findings from this work indicate that composite biochars prepared from biomass and inexpensive clay minerals are a promising adsorbent for remediating organic contaminants from water.

By the extended (G′G) method and the improved tanh function method, the exact solutions of the (2+1) dimensional Boussinesq equation are studied. Firstly, with the help of the solutions of the nonlinear ordinary differential equation, we obtain the new traveling wave exact solutions of the equation by the homogeneous equilibrium principle and the extended (G′G) method. Secondly, by constructing the new ansatz solutions and applying the improved tanh function method, many non-traveling wave exact solutions of the equation are given. The solutions mainly include hyperbolic, trigonometric and rational functions, which reflect different types of solutions for nonlinear waves. Finally, we discuss the effects of these solutions on the formation of rogue waves according to the numerical simulation.