Agglomeration of the industry significantly impacts economic performance and environmental sustainability. In line with its strategic context of striving to achieve carbon reduction targets, China is making efforts to optimize the producer services landscape to reduce carbon emissions. Understanding the spatial correlation between industrial agglomeration and carbon emissions is particularly crucial against this background. Based on POI and remote sensing data of China’s Yangtze River Economic Belt (YREB), the paper adopts the mean nearest neighbor analysis, kernel density analysis, and standard deviation ellipse to portray the agglomeration of producer services. Then uses Moran's I to present the spatial distribution characteristics of carbon emissions. Accordingly, the spatial heterogeneity of producer services agglomeration and carbon emissions is showed using the Geographic detector so as to provide strong support for industrial structure optimization and sustainable development. Here are some of the conclusions drawn from the study: (1) Producer services are a significant state of agglomeration in the provincial capitals and some central cities, with similar agglomeration patterns. (2) Carbon emissions exhibits significant spatial aggregation characteristics, with the spatial distribution pattern of "High west–Low east". (3) Wholesale and retail services industry is the primary risk factor that causes spatial differentiation of carbon emission intensity, "leasing and business services industry-wholesale and retail services industry" is the key interaction factor of the spatial differentiation. (4) Carbon emissions shows a downward trend followed by an upward trend as producer services agglomeration increases.