Herein, we report a nickel-catalyzed remote arylalkylation of unactivated γ,δ- and δ,ε-alkenes in alkenyl carbonyl compounds with arylboronic acids and alkyl halides. Kinetically and thermodynamically disfavored 6- and 7-membered nickelacycles...

Photoredox/transition-metal dual catalysis could efficiently construct C‒N bond by cross-coupling reaction. The limitations of low recovery, low utilization rate and high cost have hindered the application and development of low-cost...