The activation and functionalization of C-F bonds under mild conditions can serve as an important tool for organic syntheses including the modification of pharmaceuticals or agrochemicals and the synthesis of...
Oxidative radical cascade spirocyclization and dearomatization of biary ynones with a variety of hydrocarbons including toluenes, ethers, ketones, and alkanes has been developed to construct alkyl substituted spiro[5.5]trienones.
We disclosed a general visible light-promoted and electron-donor-acceptor complex enabled cascade reaction of alkynes via a radical addition/cyclization cascade sequence under photocatalyst-, base-, oxidant- and metal-free conditions. The arylsulfinic acid...
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