Three novel phenothiazine-substituted oxime esters (Ph-PTZ-OXE, TPA-PTZ-OXE and CZ-PTZ-OXE) applicable to visible laser diodes (405 nm and 455 nm) were successfully designed and synthesised.
A new angle: The insertion of a 2,2′‐biphosphole subunit into π‐conjugated systems offers a new way to control the HOMO–LUMO gap. Tuning of the dihedral angle (θ) between the two phosphorous heterocycles, either by metal coordination or covalent bonding through the P substitution can lead to control of the band gap. These new π‐conjugated systems can be used as emitting materials in white organic light‐emitting devices (WOLEDs).
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