Abstract:The aim of the study was to evaluate the impact of potential pollution sources, mainly from the upstream anthropogenic sources and port-related activities. The investigated area covered a wide range of anthropogenic impacts (e.g., industrial wastes, storm water runo , accidental oil spills, intentional discharges and shipping activities). The quality of water and sediments was assessed using standard methods, as physical-chemical parameters, chemistry and biology (microbiology, ecotoxicology) aiming to gure the level of pollution and the e ect of portrelated activities. Seawater quality results agreed generally with environmental standards. Though, in some samples the concentrations of sulphates (mg/l) and heavy metals (µg/l), as B, As and Se exceeded the recommended limits, without posing a serious environmental concern. Most of the surface sediment samples contain critical levels of hydrocarbons (C>12), (mg/kg), polycyclic aromatic hydrocarbons (ng/g) and polychlorobiphenyls (ng/g). For some heavy metals (mg/kg), exchangeable concentrations were found to be very close or above the regulations. The signicance of this study is incontestable taking into account the lack of previous relevant historical data of this area. In this sense, it was possible to indicate, in general, good environmental conditions, despite the industrial and concentrated local port-related activities in the investigated area.

The aim of this paper is to show the results of two methodological approaches applied for decontamination of the Midia Port dredged sediment to assess their potential reusability. Firstly, the sediment samples were defined in physical, chemical, microbiological and ecotoxicological terms. The results were compared to the limit values established by environmental regulations for dredged sediment management. Some sediment samples exposed a very high concentration of hydrocarbons; the sediments were classified in three categories on the basis of their level of organic/inorganic pollutants. The polluted sediment samples were subjected to the soil-washing treatment. The post treatment analysis revealed that the coarse silty and sandy fractions resulted unpolluted. The soil-washing induced the physical concentration of pollutants (i.e. C>12) in the silty-clay fraction. The wastewater from the treatment plant, once treated, showed no critical issues. After soil-washing treatment, the sediment samples were exposed to a laboratory scale 30kW RF thermal plasma source. Two types of plasma assisted treatments have been performed: the carbothermal process (to evaluate the technical feasibility of silicon extraction during material inertization) and the vitrification process (only for material inertization). Scanning electron microscopy (SEM), energy dispersion spectroscopy (EDS) withal X-ray fluorescence (XRF) and leaching tests were used to investigate the obtained material. The acquired results revealed a decontamination of the collected sediments with leaching test results below legal limits. EDS analysis showed the increment of silica (SiO2) content by about 5-7 % after the plasma treatment and that the localized extraction of silicon by the carbothermal reduction process has been obtained.

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