In this study, a tungsten oxide wire electrode is described for use as a pH electrode in a portable battery-powered flow injection analyser described previously. 1 The tungsten oxide electrode exhibits a linear response of 44.8 ± 0.5 mV change per pH unit over a wide range, pH 2-11 in the steady-state mode. In the flow injection mode, the tungsten oxide wire electrode exhibited a slope of 42.4 ± 0.9 mV per pH unit. The tungsten oxide electrode was employed to determine the pH of various alcoholic beverages and environmental water samples.
Photo‐cured calcium, potassium, and nitrate ion‐selective electrodes and Ag/AgCl wire as a chloride electrode have been integrated into a sensor array that is suitable for FIP measurements in a wall‐jet flow cell. Each sensor in the electrode‐array exhibited near‐Nernstian response over a log‐linear range between 0.1 mM and 10 mM and detection limits of 0.01 mM in the flow injection potentiometric mode. The four coated wire electrodes were used simultaneously in the flow injection mode to determine their respective determinand in various water samples and the results were in good agreement with standard analytical methods.
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