No abstract

Using the Yebes 40 m and IRAM 30 m radiotelescopes, we detected two series of harmonically related lines in space that can be fitted to a symmetric rotor. The lines have been seen towards the cold dense cores TMC-1, L483, L1527, and L1544. High level of theory ab initio calculations indicate that the best possible candidate is the acetyl cation, CH3CO+, which is the most stable product resulting from the protonation of ketene. We have produced this species in the laboratory and observed its rotational transitions Ju = 10 up to Ju = 27. Hence, we report the discovery of CH3CO+ in space based on our observations, theoretical calculations, and laboratory experiments. The derived rotational and distortion constants allow us to predict the spectrum of CH3CO+ with high accuracy up to 500 GHz. We derive an abundance ratio N(H2CCO)/N(CH3CO+) ∼ 44. The high abundance of the protonated form of H2CCO is due to the high proton affinity of the neutral species. The other isomer, H2CCOH+, is found to be 178.9 kJ mol−1 above CH3CO+. The observed intensity ratio between the K = 0 and K = 1 lines, ∼2.2, strongly suggests that the A and E symmetry states have suffered interconversion processes due to collisions with H and/or H2, or during their formation through the reaction of H3+ with H2CCO.

The emergence of chemical complexity during star and planet formation is largely guided by the chemistry of unstable molecules that are reaction intermediates in terrestrial chemistry. Our knowledge of these intermediates is limited by both the lack of laboratory studies and the difficulty in their astronomical detection. In this work, we focus on the weakly bound cluster HO3 as an example of the connection between laboratory spectroscopic study and astronomical observations. Here, we present a fast-sweep spectroscopic technique in the millimeter and submillimeter range to facilitate the laboratory search for trans-HO3 and DO3 transitions in a discharge supersonic jet and report their rotational spectra from 70 to 450 GHz. These new measurements enable full determination of the molecular constants of HO3 and DO3. We also present a preliminary search for trans-HO3 in 32 star-forming regions using this new spectroscopic information. HO3 is not detected, and column density upper limits are reported. This work provides additional benchmark information for computational studies of this intriguing radical, as well as a reliable set of molecular constants for extrapolation of the transition frequencies of HO3 for future astronomical observations.