The kinetics of the iodine-tri-iodids-iodide electrode in acetonitrile has been investigated in the temperature range from 0 to 30°C. Current/voltage curves were determined using a platinum rotating disk electrode working at 200 to 3000rpm. The anodic and cathodic current/voltage curves are characterized by two well defined waves. The total reactions related to the first and second anodic waves are respectively and
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