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An analytical solution of MHD free convective, dissipative boundary layer flow past a vertical porous surface in the presence of thermal radiation, chemical reaction and constant suction, under the influence of uniform magnetic field which is applied normal to the surface is studied. The governing equations are solved analytically using a regular perturbation technique. The expressions for velocity, temperature and concentration fields are obtained. With the aid of these, the expressions for the coefficient of skin friction, the rate of heat transfer in the form of Nusselt number and the rate of mass transfer in the form of Sherwood number are derived. Finally the effects of various physical parameters of the flow quantities are studied with the help of graphs and tables. It is observed that the velocity and concentration increase during a generative reaction and decrease in a destructive reaction. The same observed to be true for the behavior of the fluid temperature. The presence of magnetic field and radiation diminishes the velocity and also the temperature.Ó 2014 Production and hosting by Elsevier B.V. on behalf of Ain Shams University.