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Sunzmary Allylic alcohols (e.g., oct-l-en-3-01) are con-contains a tertiary allylic alcohol substituent, is nonverted, in preparative yields, into saturated ketones by reactive. We note that under the reaction conditions Pseudomonas oleovorans and this process is shown to used, ketonization of saturated alcohols, potential interinvolve independent alcohol dehydrogenase and olefin mediates in the reaction pathway from all ylic alcohols, reductase enzymes. occurs readily, with octan-2-01 being the most reactive alcohol tested. I t is apparent from the Table that reduc-

Die enzymatische Epoxidation des Octadiens (I) verläuft mit hoher Stereoselektivität unter Bildung des optisch aktiven Monoepoxids (II) und optisch aktiven Diepoxids (III) mit den angegebenen (R)/(S)‐Enantiomeren‐Zusammensetzungen..

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