The reactions of the organodichalcogenone ligands Bbit[1,1′‐(butane‐1,4‐diyl)bis(3‐methylimidazoline‐2‐thione)],Mbis [1,1′‐methylenebis(3‐methylimidazoline‐2‐selone)], Ebis [1,1′‐(ethane‐1,2‐diyl)bis(3‐methylimidazoline‐2‐selone)] and Pbis [1,1′‐(pentane1,5‐diyl)bis(3‐methylimidazoline‐2‐selone)] with gold(I/III), silver(I) and copper(I) have been studied by elemental analysis, multinuclear (1H, 13C, 19F, 31P and 77Se) NMR spectroscopy and for several products obtained the molecular structures were also established by single‐crystal X‐ray diffraction analysis. In most cases the organodichalcogenone coordinates to two metallic fragments as a bidentate bridging ligand but the ligand Mbis coordinates to silver(I) in an unprecedented tetradentate bridging‐chelate mode.