Resistive transition measurements are reported for MgB 2 strands with SiC dopants. The starting Mg powders were 325 mesh 99.9% pure, and the B powders were amorphous, 99.9% pure, and at a typical size of 1-2 µm. The SiC was added as 10 mol% of SiC to 90 mol% of binary MgB 2 [(MgB2)0.9(SiC)0.1]. Three different SiC powders were used; the average particle sizes were 200 nm, 30 nm, and 15 nm. The strands were heat treated for times ranging from 5 to 30 minutes at temperatures from 675°C to 1000°C. Strands with 200 nm size SiC additions had µ 0 H irr and B c2 which maximized at 25.4 T and 29.7 T after heating at 800°C for 30 minutes. The highest values were seen for a strand with 15 nm SiC heated at 725°C for 30 minutes which had a µ 0 H irr of 29 T and a B c2 higher than 33 T.
Recent advances in MgB 2 conductors are leading to a new level of performance.Based on the use of proper powders, proper chemistry, and an architecture which incorporates internal Mg diffusion (IMD), a dense MgB 2 structure with not only a high critical current density J c , but also a high engineering critical current density, J e , can be obtained. In this paper, a series of these advanced (or second-generation, "2G") conductors has been prepared. Scanning electron microscopy and associated energy dispersive X-ray spectroscopy were applied to characterize the microstructures and compositions of the wires, and a dense MgB 2 layer structure was observed. The best layer J c for our sample is 1.07x10 5 A/cm 2 at 10 T, 4.2 K, and our best J e is seen to be 1.67x10 4 A/cm 2 at 10 T, 4.2 K.Optimization of the transport properties of these advanced wires is discussed in terms of Bpowder choice, area fraction, and the MgB 2 layer growth mechanism.
PACS: 74.70.Ad; 74.25.Sv; 74.25.Qt; 74.62.Dh Keywords: MgB 2 , layer critical current density J c , engineering critical current density J e , internal magnesium diffusion (IMD)
Since 2001, when magnesium diboride (MgB2) was first reported to have a transition temperature of 39 K, conductor development has progressed to where MgB2 superconductor wire in kilometer‐long piece‐lengths has been demonstrated in coil form. Now that the wire is available commercially, work has started on demonstrating a MgB2 wire in superconducting devices. This article discusses the progress on MgB2 conductor and coil development, and the potential for MgB2 superconductors in a variety of commercial applications: magnetic resonance imaging, fault current limiters, transformers, motors, generators, adiabatic demagnetization refrigerators, magnetic separation, magnetic levitation, superconducting magnetic energy storage, and high‐energy physics applications.
We report a systematic study on the effect of sintering temperature on the phase formation,
critical current density, upper critical field and irreversibility field of nanoscale SiC doped
MgB2. Bulk and Fe sheathed wires doped with different nano-SiC particle sizes
have been made and heat treated at temperatures ranging from 580 to
1000 °C. A systematic correlation between the sintering temperature, normal state resistivity, RRR,
Jc,
Hc2,
and Hirr
has been found in all samples of each batch. Samples sintered at a lower temperature have
a very fine and well consolidated grain structure while samples sintered at a high temperature
contain large grains with easily distinguishable grain boundaries. Low temperature sintering
resulted in a higher concentration of impurity precipitates, larger resistivity, higher
Jc up to 15 T and
lower Tc values. These
samples show higher Hc2
and Hirr
at T near
Tc but
lower Hc2
near T = 0
than samples sintered at high temperature. It is proposed that huge local strains produced by
nano-precipitates and grain boundary structure are the dominant mechanism responsible for higher
Hc2 at
T
near Tc. However, higher impurity scattering due to C substitution is responsible for higher
Hc2
in the low temperature regime for samples sintered at a higher temperature. In addition to high
Hc2, it is also proposed that the large number of nano-impurities serve
as pinning centres and improve the flux pinning, resulting in higher
Jc
values at high magnetic fields up to 15 T.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.