In the title compound, C17H19NO3S2, the maximum deviation of atoms in the 2H-chromene ring system is 0.0097 (14) Å and the piperidine ring adopts a chair conformation. The dihedral angle between the 2H-chromene ring and the piperidine ring (all atoms) is 87.59 (8)°. In the crystal, inversion dimers linked by pairs of C—H⋯O interactions generate R
2
2(22) loops. Further C—H⋯O hydrogen bonds link the dimers into [110] chains and weak aromatic π–π stacking [shortest centroid–centroid distance = 3.824 (8) Å] is also observed.
In the title compound, C31H38O3, the central benzene ring makes dihedral angles of 66.06 (9) and 65.21 (8)°, respectively, with the benzyl and 4-decylphenyl rings.
In the title compound, C23H19Cl2N5OS, the triazole ring makes dihedral angles of 24.81 (18), 69.94 (19) and 35.68 (18)° with the dichlorophenyl, benzene and methoxyphenyl rings, respectively. An intramolecular N—H⋯N hydrogen bond occurs. In the crystal, inversion dimers linked by pairs of N—H⋯S hydrogen bonds occur. In addition, there are weak C—H⋯π interactions involving the dichlorophenyl and triazole rings.
In the title compound, C17H10F6N4·H2O, the pyridine ring is not coplanar with the quinoline ring system; the dihedral angle between the two planes is 21.3 (1)°. One of the trifluoromethyl group is disordered over two orientations with occupancies of 0.70 (1) and 0.30 (1). The water molecule is disordered over two positions with occupancies of 0.76 (1) and 0.24 (1). In the crystal, the water molecule is linked to the main molecule via N—H⋯O and C—H⋯O hydrogen bonds, and inversion-related pairs are linked via O—H⋯N hydrogen bonds. In addition, a weak π–π interaction is observed between the pyridine ring and the pyridine ring of the quinoline unit, with a centroid–centroid distance of 3.650 (2) Å.
In the title compound, C17H15NO2S2, the 3H-benzo[f]chromene ring system is distinctly twisted; the dihedral angle between the pyran ring and its opposite benzene ring is 9.11 (8)°. The N,N-dimethylcarbamodithioate residue lies almost perpendicular to the pyran ring [dihedral angle = 85.15 (7)°]. In the crystal, weak C—H⋯O hydrogen bonds link the molecules into C(10) chains propagating in [001].
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