The present study was designed to determine the LC50 of some insecticides commonly used against Helicoverpa armigera and their comparative efficacy against the insect pest. The second instar larvae of H. armigera reared in the laboratory were selected for leaf dip bioassay. Two types of insecticides viz. conventional (deltamethrin and bifenthrin) and new chemistry (spinosad and indoxacarb) were assessed in the present studies. The results revealed that bifenthrin was more toxic to the second instar larvae of H. armigera at all the doses with lower LC50 value of 120.007 ppm as compared to deltamethrin with the highest LC50 value of 292.404 ppm. Among the new chemistry insecticides, indoxacarb proved to be more toxic than spinosad with LC50 of 5.592 ppm. LC50 of spinosad was 8.201 ppm showing 1.46 times less toxicity than indoxacarb.

Pharmaceutical waste and presence of hazardous pollutants in them is a growing concern due to their fate, origin, higher rate of utilization and varying nature of active ingredients resulting in water contamination. However, there is few research on the graving nature of the problem. Cascading impacts on human and ecosystems can be expected from contaminated groundwater and other aquatic channels. While, various technologies used and studied for the removal/reduction/sedimentation of pharmaceutical pollutants. At the initial stages, level of toxicity should check with respect to flora, fauna, environment, and human health. Furthermore, the production of by-products from pharmaceutical pollutants should also be checked and regulated. These by-products can be much more toxic, than the original contaminants and can exert significant toxic effects. It was concluded that there should be ongoing efforts to reduce the cost associated with pharmaceutical waste and their pollutants removal processes to ensure sustainability in the environment and human being. Keywords: nanoparticles, oxidation, pharmaceutical pollution, radiation, sustainable environment, toxicity

B rassica spp. family Cruciferae has a prime position as a resource of edible oil for humans (Mandal et al., 2012). In Pakistan, the most abundant species of Brasicae comprise Brassica campestris L., B. juncea L. and B. napus L. (Khan and Begum, 2005). It occupies an area of 2,22,000 hectares with 4,88,000 tons of production (Anonymous, 2021).

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