In the present work lead based perovskite ceramic Pb (Zr0.52Ti 0.38Li0.1)O3 was prepared via high planetary mill. The green body was sintered at 850 °C. The effect of 0.1 wt % Li+ addition on the sintering temperature, microstructure and on dielectric properties of Pb (Zr0.52Ti0.48)O3 were investigated. Thermal analysis of ceramic reveals that the PZT can be synthesized at low temperature. XRD diffractrogram shows the presence of secondary phase (lead oxide PbO) in the sample. The maximum dielectric constant was observed at low frequency which was 1163.22 at 20 Hz.
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