In this paper, bismuth ferrite (BFO) particles synthesized by controlled
hydrothermal process, where the particles of small sizes and with high purity
were obtained. Structural analysis showed that non-annealed powder can be
perfectly fitted to rhombohedral space group R3c and contains a very small
amount of secondary phase, whereas the final product (annealed at 800?C)
represents single-phase perovskite powder with high crystallinity. HRTEM
analysis confirmed existence of twin stacking faults, which are responsible
for enhanced magnetic properties. EPR measurements suggested existence of
electrons trapped by vacancies or defects. It has been proposed that
existence of Fe3+?OV defect complex could be generated at elevated
temperatures followed by formation of trivalent Fe ions, which intensely
provide local 3d moments. [Projekat Ministarstva nauke Republike Srbije, br.
172015, br. 172018 and i br. III 45012]
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