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Structure and Bonding in Gold(i) Compounds. Part 2.t Mossbauer Spectrum of Linear Gold([) Complexes

Abstract.Chloro ( The coordination in MONO is nearly linear, with a P-Au-CI angle of 177.0 (2) ° and Au-P and Au-C1 bond distances of 2.242(4) and 2.279 (5)A, respectively. In the BIS complex the C1 is ionic. The cation [(Cy3P)2Au] + is at a center of symmetry, so the two phosphines are staggered with exactly linear P--Au-P coordination and the P-Au distance is 2.321 (2) A.

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