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To investigate the interaction between the water framework and a guest molecule in a clathrate hydrate, high-pressure Raman scattering experiments on nitrogen guest molecules have been performed. The pressure dependence of the N2 vibron(s) at room temperature (295 K) has been determined and a new phase transition has been discovered at 0.84 GPa.

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Disclaimer/Complaints regulationsIf you believe that digital publication of certain material infringes any of your rights or (privacy) interests, please let the Library know, stating your reasons. In case of a legitimate complaint, the Library will make the material inaccessible and/or remove it from the website. Abstracr The experimental phase behaviour of binary mixtures of nitrogen with three very different components is discussed. The phase diagrams have also been determined theoretically but with modest success. It will be shown thal our bowledge of the unlike potential parameters is insufficient.