A cubic metal-organic framework with an unprecedented octanuclear secondary building unit (SBU) was isolated. The obtained SBU is composed of 8 Co(II) ions at each vertex, 6 μ4-OH groups at each face, and 12 cpt(-) ligands framing the metal core. The cuboctahedra arrange in a ubt framework topology, eliciting a highly symmetrical MOF structure. Magnetic measurements as well as DFT calculations on this crystalline MOF reveal intramolecular antiferromagnetic coupling between Co(II) ions in the octanuclear SBU.
This case follows Katie, a sport manager, as she researches Swimming Canada, an early adopter of integration (governing both able-bodied and para-swimming within one organization). The case demonstrates the organizational challenges and opportunities of integrating parasport and the able-bodied counterpart into one national sport governing body. While philosophically integration seems to be a good direction, the case of Swimming Canada demonstrates some of the key issues that need to be considered around access and inclusion, human capital resources for sport delivery, governance mechanisms, and the structure of sport that is influenced by many different social constructs. This case is particularly useful for addressing how sport policy and politics impact organizational change, inclusion, equity, and sport governance. The case is appropriate for use at the undergraduate and graduate levels.
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