The cobalt-mediated cycloaddition with γ-alkylidenebutenolide diverges dramatically from what is expected, leading to unprecedented polycyclic scaffold cobalt(iii)-complexes. The mechanism of this reaction has been studied by DFT calculations.
A structurally diverse range of chiral diaryliodonium salts have been synthesised which have potential application in metal-free stereoselective arylation reactions.
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