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In this work, the interactions between two key additives in current lubricants (ZDDP and MoDTC) and the effect on tribofilm formation and tribofilm evolution under boundary lubrication are studied. The chemical and tribological characteristics of the tribofilms are probed using measurement of friction, wear and film characteristics. Tribofilms have been examined by energy dispersive X-ray analysis (EDX) and X-ray photoelectron spectroscopy (XPS). In order to investigate the morphology of the reaction films formed, atomic force microscopy (AFM) was used. In this work, for the first time, a link between a proposed MoDTC breakdown mechanism and MoDTC tribofilm characteristics, measured on experimentally derived tribofilms, is made.

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Mathematical models of piston ring dynamics and lubrication are sensitive to the boundary conditions adopted to describe the cavitation occurring in the diverging outlet region of the lubricant film between the piston ring and cylinder wall. In this paper, such sensitivity is investigated by applying different models of gaseous cavitation, flow separation and fluid film reformation to the analysis of a single compression ring from a diesel engine. Significant differences are predicted in hydrodynamic pressure profiles, lubricant film boundaries, lubricant film thickness, oil flow and friction. Such indications of substantial differences in piston ring operating characteristics associated with the distinct cavitation boundary conditions considered highlights the need for further research in this field. However, the lack of detailed experimental data to validate the predictive models suggests that future progress must be based upon combined theoretical and experimental approaches to the problem. It is postulated that boundary conditions based upon Reynolds cavitation and fluid film reformation may be applicable at high loads, and fluid film separation of a form proposed by Coyne and Elrod at low loads.