The synthesis of the metalhydride Cp*(L′)) is achieved by a cyclohexane to cyclohexene transformation at the N-heterocyclic carbene ligand based on a CH-activation/β-hydrogen migration process at the Ir(III) center under mild conditions. The synthetic route to Cp*-(L′)IrH + OTfand NMR spectroscopic and X-ray structural data are presented.
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