Catalytic ensembles suitable for alkene epoxidation with aqueous hydrogen peroxide are now accessible. They are made by grafting robust titanium silsesquioxane sites onto dimethylsiloxane polymers (see picture) followed by cross‐linking to three‐dimensionally netted polymers.
Katalytische Ensembles für die Alkenepoxidierung mit wässrigem Wasserstoffperoxid sind nun zugänglich. Die Herstellung solcher Systeme gelingt durch Pfropfung robuster Titansilsesquioxan‐Aktivzentren an Dimethylsiloxanpolymere (siehe Bild) und nachfolgende Quervernetzung zu dreidimensionalen Polymeren.
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