The potential of a fibre luminescent solar concentrator has been explored by means of both analytical and ray-tracing techniques. Coated fibres have been found to be more efficient than homogeneously doped fibres, at low absorption. For practical fibres concentration is predicted to be linear with fibre length. A 1 m long, radius 1 mm, fibre LSC doped with Lumogen Red 305 is predicted to concentrate the AM1.5 g spectrum up to 1100 nm at normal incidence by ~35 x. The collection efficiency under diffuse and direct irradiance in London has been analysed showing that, even under clear sky conditions, in winter the diffuse contribution equals the direct.

Optical characterisation methodologies are employed to validate a nanorod self-alignment technique for use in luminescent solar concentrators (LSCs). The nanorods utilised in this work were CdSe/CdS core/shell nanorods, and the self-alignment technique relied on the evaporation of a highly concentrated nanorod/xylene solution onto a glass substrate. Position and angular dependent light absorptivity measurements revealed evidence of vertical nanorod alignment over a limited region at the centre of the LSC sample. Vertical nanorod alignment is beneficial for absorbing diffuse/scattered sunlight and provides for a high light trapping efficiency in the LSC.

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In this work we aim to investigate flexible luminescent solar concentrators (LSCs) for the purpose of portable power generation. We will focus on Surelight® PE-610, which is a tandem fluorophore consisting of R-Phycoerythrin and Rhodamine, as well as PbSe nanorods, as the luminescent species. The luminescent quantum yield, LQY, of PE-610 was measured as 53% in buffer solution, and 75% when deposited in a thin-film. Computational simulations show that a 25cm by 25cm LSC with a 0.1mm thick thin-film containing PbSe nanorods, a LQY of 70% and a substrate thickness of 3mm has an optical efficiency of 4.5±0.1%. An identical LSC with a 0.5mm thick substrate had an optical efficiency of 1.7±0.1% meaning substrate thickness is a key factor for flexible LSCs. A primary advantage of PE-610 as a LSC material is that it is bio-derived, and therefore cheap and abundant. The PbSe nanorods have the advantage of a broad absorption spectrum, though the LQY used is still speculative at this time

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