New complexes of dithiocarbamate of the general formula [M(3-MeoPrdtc) 2 ] and [M(3-MeoPrdtc) 2 .nL] Where M= Fe(ΙΙ), Co(ΙΙ), Ni(ΙΙ), Cu(ΙΙ) and Zn(ΙΙ), and (3-MeoPrdtc) =3-Methoxypropyldithiocarbamate, and n=2 when L= pyridine, Isoquinoline, γ-picoline, 3,5-lutidine, n=1 when L= ethylenediamine, (1,10)-phenanthroline, have been prepared and characterized by metal analyses, infrared, conductance measurements, electronic absorption spectra and suscetptibility measurements. Magnetic moment and electronic spectra, indicate that the complexes of the type [M(3-meoprdtc) 2 ] are of tetrahedral geometry while the complexes of the type [M(3-meoprdtc) 2. nL] have octahedral geometry.