does increase the sensitivity of the collection step, it does so at the expense of selectivity.Equation 9 predicts a 14-mV anodic stripping peak potential shift as the scan rate is increased from 1 to 3 V/min. A 13-mV anodic shift was observed experimentally. The stripping electrode potential at which the collection peak is observed shifts 29 mV anodically over the same scan rate range, resulting in the increase in with scan rate indicated in
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