Diglycidyl ether of bisphenol A (DGEBA) epoxy resin was cured with hardeners aliphatic amine triethylenetetramine (TETA). Differential scanning calorimetry (DSC) technique was utilized to study the kinetics of cure of (DGEBA)-(TETA) system, diverse hardener/resin ratios were studied, (5, 13and 20) phr. Isothermal as well as dynamic experiments were carried out of the above mentioned DGEBA/TETA system with three hardener/resin ratios, and cure kinetics were investigated at four temperatures (30, 45, 60 and 80) °C using (DSC) technique. The process of isothermal cure was simulated by the diffusion model (modified Kamal's model and four-parameter autocatalytic model. The obtained outcomes are in good agreement with the experimental results in the early and late cure stages. The events declare that complete cure at 80 °C attains at the stoichiometric ratio (13 phr).

In this study viscosity ) η ( of diglycidyl ether of bisphenol A / triethylenetetramine (DGEBA/TETA) system were measured through curing using a Brookfield viscometer at four different temperatures (30, 45, 60 and 80) °C. The measurements were carried out for two hardener/resin ratios (13 and 20) phr. The gel time was calculated for each hardener/resin ratio formulation; from the viscosity experimental data. The results showed that the gel time decrease with increasing curing temperature for each hardener/resin ratio formulation. Viscosity profiles were described by a model based on the Boltzmann function. The fitted results agreed well with the experimental values.