A set of anthracene containing polyfluorenes (PFs) having 9,10-diphenylanthracene with alkyl substituents and aniline containing fluorenes were prepared. Commonly, light-emitting polymers were synthesized using expensive palladium-like catalysts. In the present work, palladium was replaced by copper as a cost-effective PF synthesis catalyst, which is also suitable for large-scale polymer synthesis. Synthesized PFs emit light in the blue region with a bandgap of 2.87–2.90 eV. Thermally stable PFs had a decomposition temperature of more than 305°C and a glass transition temperature of 125–138°C. PFs were soluble in organic solvents and had a molecular weight of around 21,700–25,500. The electrochemical study of these PFs showed low level of highest occupied molecular orbital (HOMO) energy of −5.16 to −5.26 eV, which was significantly higher than that of PF (5.7 eV). These findings suggested that the resulting PFs could be used as a component of the light-emitting diode.

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