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1O( 1 D)+HCl(v=0; j=0) ClO+H and its isotope exchange reaction-O( 1 D)+DCl(v=0; 2 j=0) ClO+D are studied in the collision energy range 14.0 -20.0 kcal/mol based on the 3 potential energy surface -1 A' state. Reaction probabilities, integral cross sections, the two 4 angular distribution functions (concerning the initial/final velocity vector, and the product 5 rotational momentum vector), and the product rotational alignment parameters are calculated 6 as a function of the collision energy for the two reactions. The four generalized polarization 7 dependent differential cross sections are presented to manifest the polarization characters. 8 Also, the effect of the collision energy and the kinetic isotope effect are studied. 9