Event extraction aims to identify an event and then extract the arguments participating in the event. Despite the great success in sentencelevel event extraction, events are more naturally presented in the form of documents, with event arguments scattered in multiple sentences. However, a major barrier to promote documentlevel event extraction has been the lack of large-scale and practical training and evaluation datasets. In this paper, we present Do-cEE, a new document-level event extraction dataset including 27,000+ events, 180,000+ arguments. We highlight three features: largescale manual annotations, fine-grained argument types and application-oriented settings. Experiments show that there is still a big gap between state-of-the-art models and human beings (41% Vs 85% in F1 score), indicating that DocEE is an open issue. DocEE is now available at https://github.com/ tongmeihan1995/DocEE.git.