The Pampa Húmeda region in Argentina is characterized by soybean, wheat, and maize production, with intensive application of agrochemicals such as herbicides and insecticides. We used a joint probabilistic approach to analyze the probabilities for environmental chlorpyrifos concentrations measured in the Pampa Húmeda to exceed acute or chronic hazardous concentration for 5% of the species (HC5) values estimated from species sensitivity distributions for aquatic species. Chlorpyrifos concentrations in water ranged from 0.0005 to 10.8 µg/L, with a median of 0.013 µg/L. The HC5 limits were 0.0637 µg/L for acute and 0.0007 µg/L for chronic effects. The probabilities for chlorpyrifos environmental concentrations to exceed the HC5 values ranged from 35% (acute effects) to 96% (chronic effects). Water quality criteria (WQC) for the protection of aquatic life were also frequently exceeded (by 48–87%) for both acute and chronic effects. Together with published threshold limit values from mesocosm studies, these data suggest that macroinvertebrate communities can be severely affected by the reported environmental concentrations of chlorpyrifos. Indeed, changes in the macroinvertebrate assemblage in the Pampa Húmeda have been correlated with chlorpyrifos levels in sediments. Nevertheless, the actual impact needs to be ascertained by assessing the recovery rate of macroinvertebrate populations in this region. Considering the HC5 for chronic effects and the threshold limits for macroinvertebrate community level effects, we propose 0.7 ng/L as a new WQC to effectively protect aquatic life from long‐term exposure to chlorpyrifos. Environ Toxicol Chem 2019;38:1748–1755. © 2019 SETAC.

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Chlorpyrifos (O,5, phosphorothioate) is a broad-spectrum organophosphate insecticide and acaricide, widely used in our country. Nowadays, it is the principal insecticide in the market employed for agricultural purposes. A number of studies tending to study the affinity of different pesticides with soil have been performed, but only a few refer to chlorpyrifos. Because of its intensive use, a wide range of terrestrial ecosystems may be contaminated with chlorpyrifos, and there is a need to evaluate its environmental behavior and effects. The aim of our work is to study the interaction and persistence of a commercial formulation of chlorpyrifos on an agricultural soil from Provincia de Buenos Aires, Argentina. In this case, recovery percentages increased with the increase of initial concentration of the pesticide until a concentration of about 25 ppm is reached, and then a decrease was observed. The half-time life was not affected by an increase in chlorpyrifos concentration.

Atrazine (ATZ) is the third most widely used herbicide in Argentina (10 000 t year−1) and is approved for sugar cane, flax, corn, sorghum, and tea. An assessment of the ATZ environmental impacts was conducted at the request of the Ministry of Environment and Sustainable Development of Argentina. A review of 541 national and international technical and scientific reports and a survey among agricultural technicians, applicators, and producers was done. The survey revealed that 94% of ATZ applications are terrestrial and use diversion exists, associated mainly with soybean cultivation. Atrazine was reported at high frequencies (50%–100%) in surface and groundwater, sediments, and soils, sometimes exceeding permitted limits. Several sublethal effects induced by ATZ on invertebrate and vertebrate species were found, sometimes at concentrations lower than those in water quality guidelines (<3 µg L−1) or the environmental concentrations found in Argentina. Available epidemiological or human health studies of local populations are extremely scarce. This assessment also demonstrated that herbicides are ubiquitous in the environment. The investigation highlights the need for further studies assessing the adverse effects of ATZ on local species, ecosystems, and human health. Therefore, the precautionary principle is recommended to promote better application standards and product traceability to reduce volumes entering the environment and to avoid use deviation. In addition, this work concluded that there is a need for reviewing the toxicological classification, establishing buffer zones for ATZ application, introducing specific management guidelines, and expanding local studies of toxicity, ecotoxicity, and human epidemiology for environmental and health risk assessments. This study could also serve as a preliminary risk evaluation for establishing a final regulatory action and for considering ATZ inclusion in Annex III of the Rotterdam Convention. Finally, the requirements to consider its inclusion in Annex A (Elimination) or B (Restriction) of the Stockholm Convention were evaluated and discussed, and information on the potential of long‐range transport was the only criterion with no information to consider. Integr Environ Assess Manag 2023;19:684–697. © 2022 SETAC