The application of immobilized sulfuric acid on silica gel (H2SO4-SiO2) as an efficient and easily reusable solid catalyst was explored in the synthesis of novel α-acyloxycarboxamide derivatives via a Passerini reaction of benzoic acid, aldehyde/ketone, and isocyanides. The Passerini adducts were obtained in high to excellent yields within 10 min in aqueous media under catalytic conditions. The key advantages of the process include a short reaction time, high yields, the catalyst’s low cost, and the catalyst’s reusability.

No abstract

C11H7BrO4, triclinic, P1̄ (no. 2), a = 4.3164(5) Å, b = 10.7922(12) Å, c = 11.1521(11) Å, α = 98.075(4)°, β = 100.741(4)°, γ = 95.325(5)°, V = 501.55(9) Å3, Z = 2, Rgt(F) = 0.0203, wRref(F2) = 0.0544, T = 200(2) K.

No abstract

No abstract