In the title compound, [Pd(C17H13N2O)2], the PdII atom is tetracoordinated by two N atoms and two O atoms from two bidentate methylphenyldiazenylnaphtolate ligands, forming a square-planar complex. The two N atoms and two O atoms around the PdII atom are trans to each other (as the PdII atom lies on a crystallographic inversion centre) with O—Pd—N bond angles of 89.60 (11) and 90.40 (11)°. The distances between the PdII atom and the coordinated O and N atoms are 1.966 (3) and 2.009 (3) Å, respectively.
Despite many studies on benzofuran-derived azadiene have been reported, multi-component studies have scarcely been reported on this heterocyclic skeleton. The first cascade three-component acyloxylation of diazos with acids and azadienes...
Rh(III)-catalyzed three-component C−H bond functionalizational protocol has been successfully applied to access complex polycyclic BINOL derivatives in which the formation of intermediate amides occurred in situ from aldehydes and amines....
Ir(III)-catalyzed C−H alkylation of BINOL units has been well examined by allyl alcohols as coupling partners. Under the advantage of pyridine guiding group, the efficient protocol allows the rapid synthesis...
In recent years, continuous flow technology have been applied to C−H activation to improve reaction efficiency. Herein, various imines and alkynes have been smoothly applied to continuous flow system. A series of spirocyclic sultams and isoquinolines can be obtained in excellent yields through [3+2] or [4+2] annulation reactions under relatively mild conditions.
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