Measurements
on density and viscosity at atmospheric pressure for
the ternary system 1,2,3,4-tetrahydronaphthalene (1) + isopropylcyclohexane
(2) + cyclopropanemethanol (3) and three corresponding binary systems
from (293.15 to 343.15) K have been carried out over the whole composition
range. The excess molar volumes (V
m
E) and viscosity deviations (Δη) of the ternary
system have been derived from the experimental data and then fitted
to the Cibulka, Singh, Redlich–Kister, and Nagata–Tamura
equations, respectively. The binary subsystems were correlated by
Redlich–Kister equation. For the system of 1,2,3,4-tetrahydronaphthalene
+ isopropylcyclohexane, the curve of the V
m
E reveals a wing shape. The V
m
E values are positive for the other two binary systems
of 1,2,3,4-tetrahydronaphthalene + cyclopropanemethanol
and isopropylcyclohexane + cyclopropanemethanol. While
the value of Δη for all three binary systems is negative
over the entire composition range. The results are interpreted with
molecular interactions and structural effects.
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