For the application in flexible electrochromic devices (ECDs) on plastic substrates, a new polyurethane-based gel electrolyte was manufactured. In this context, the curing behavior and the influence of the proportion of solvent and salt on the ion conductivity as well as the optical and mechanical properties were investigated. Furthermore, the stoichiometric ratio of the polyurethane matrix was varied to influence the ion conductivity. As an isocyanate component, the aliphatic difunctional polyisocyanate prepolymer, synthesized by Hexamethylen-1,6-diisocyanat (HDI), was chosen since the resulting polyurethane is considered to be particularly lightfast, color-stable and temperature-resistant and therefore frequently used for paints and coatings. As polyol a trifunctional polyetherpolyol was selected to form a wide-meshed crosslinked matrix to achieve a mechanically stable but flexible electrolyte, that enables the processing and bending of film-based ECDs. The additives amount and the matrix stoichiometric ratio affected the curing behavior and curability. The salt content had almost no influence on the measured properties in the chosen experimental space. Solvent content had a great influence on ion conductivity and mechanical properties. An understoichiometric ratio of the polyurethane matrix (0.85) increases the ion conductivity and the mechanical flexibility, but also the optical properties in a negative manner. The best specific ion conductivity with 10−5 S/cm was reached with an understoichiometric ratio of 0.85 and a high solvent content (30 wt%). Concluding, due to its high flexibility and transmittance, color neutrality and sufficient ion conductivity, the application of the researched electroyte in ECDs might be suitable. A demonstrator ECD was successfully manufactured and conducted.

Liquid silicone rubber (LSR) is primarily used in injection molding. Foamed molded parts made of LSR are almost nonexistent because the process reliability of LSR foam injection molding is currently not given. It makes sense to have suitable foaming processes for this material as well, because the density of this elastomer is about 1.15 g cm−3. With the injection molding process presented herein for foaming LSR, density reductions of up to 40% can be achieved. In this process, up to 3% by weight of water is added to the material. In addition, the hardness of the component changes, it becomes softer. Especially in the case of hardness, the process parameter mold temperature has a decisive influence, as it determines the pore size in the component. Herein, the structural properties of the silicone foam are now discussed as a function of the process parameters and additives for foaming. Thus, with the new process, material can be saved, the haptic properties of components can be changed, and a stable processing method for foamed components made of LSR is found.

The adhesion of self-adhesive liquid silicone rubbers to thermoplasts is only possible for a few selected material combinations without a surface pretreatment. A UV pretreatment is effective for polycarbonate and short irradiation periods are sufficient. To clarify the required irradiation conditions that result in an improvement of adhesion, the varying irradiation conditions were assessed. FTIR-ATR spectroscopy was used for surface analysis to characterize the change in the polymer surface.

The influence of thermomechanical stress on the conductivity of indium tin oxide (ITO)-coated polycarbonate (PC) films was investigated. PC is the industry’s standard material for window panes. ITO coatings on polyethylene terephthalate (PET) films are the main commercially available option; as such, most investigations refer to this combination. The investigations in this study aim to investigate the critical crack initiation strain at different temperatures and crack initiation temperatures for two different coating thicknesses and for a commercially available PET/ITO film for validation purposes. Additionally, the cyclic load was investigated. The results show the comparatively sensitive behavior of the PC/ITO films, with a crack initiation strain at room temperature of 0.3–0.4% and critical temperatures of 58 °C and 83 °C, with high variation depending on the film’s thickness. Under thermomechanical loading, the crack initiation strain decreases with increasing temperatures.

Multi-component injection moulding of liquid silicone rubbers (LSRs) in combination with thermoplastics is becoming increasingly important in plastics processing. This is also increasing the need to combine previously incompatible materials economically. This article shows how materials available on the market can be quickly combined in an injection-moulding process using a relatively simple pretreatment method – UV irradiation. In addition, this article discusses how long the activity of the pretreatment method persists and what effect this has on the adhesive bond. Finally, it is shown how partial adhesion of LSR to polycarbonates can be achieved.