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Glacial diamictites, with ages ranging from $2900 to 0.01 Ma, record the changing composition of the upper continental crust through time (Gaschnig et al., 2014). Li concentrations and isotopic compositions, combined with Pb isotopic compositions, chemical index of alteration (CIA) values and relative Sr concentrations are used here to assess the degree of chemical weathering recorded in these deposits and the origin of this signature. The d Li values of most of the diamictites (ranging from À3.9 to +3.5) are lower than those of mantle-derived basalts (+3.7 ± 2, 2r), and the low d7 Li values are generally accompanied by high CIA and low Sr/Sr * values (or Sr depletion factor, Sr/Sr * = Sr/(Ce * Nd) 0.5 ), reflecting a weathering signature that may have derived from pre-depositional, syn-depositional, and/or post-depositional weathering processes. Profiles through three glacial diamictites with relatively high CIA (a fresh road cut of the Neoproterozoic Nantuo Formation (CIA = 62-69), and drill cores through the Paleoproterozoic Timeball Hill (CIA = 66-75) and Duitschland Formations (CIA = 84-91)) do not show evidence of significant post-depositional weathering. High Th/U, reflecting loss of uranium during oxidative weathering, is seen in all Paleozoic and Neoproterozoic diamictites and a few Paleoproterozoic deposits. Pb isotopic systematics suggest that this signature was largely inherited from preexisting crust, although a subset of samples (the Neoproterozoic Konnarock, Paleozoic Dwyka, and several of the Paleoproterozoic Duitschland samples) appears to have experienced postdepositional U loss. Modern glaciomarine sediments record little weathering (CIA = 47, Sr/Sr * = 0.7, d7 Li = +1.8), consistent with the cold temperatures accompanying glacial periods, and suggesting that limited syn-depositional weathering has occurred. Thus, the chemical weathering signature observed in ancient glacial diamictites appears to be largely inherited from the upper continental crust (UCC) over which the glaciers traversed. The strength of this weathering signature, based on the CIA, is greatest in the Mesoarchean and some of the Paleoproterozoic diamictites and is weaker in the Neoproterozoic and Phanerozoic glacial diamictites. Combining these data with data for Archean shales and other types of post-Paleoproterozoic sedimentary rocks (i.e., shales, mudstones, etc.), it appears that post-Paleoproterozoic upper continental crust experienced less intense chemical weathering, on average, than Archean and Paleoproterozoic upper continental crust.

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Plinian pumice fall from the Holocene eruption of Mount Mazama in the Cascade volcanic arc is an unconfined, perched aquifer in south-central Oregon. The pumice aquifer provides near-surface groundwater storage that maintains biologically diverse wetland environments. Wetland environments reflect post-eruption disruption of the once uniform pumice blanket by fluvial and lacustrine processes operating within the template of the pre-eruption landscape. In the 8.6 km 2 Round Meadow watershed the pumice aquifer interacts with a seasonally flooded meadow, fen, springs, and perennial stream. The laterally uniform, isotropic pumice aquifer is disrupted by flat-bottomed ephemeral stream valleys that drain to the seasonally flooded meadow. Surface water levels in the seasonally flooded meadow are controlled by a knickpoint developed on bedrock. The underlying aquifer is confined by a layer of glass-rich diatomaceous silt grading upward to organic-rich silt. Here, the aquifer is comprised of remnants of the pumice deposit, lag sand, and reworked pumice. The water level in the confined aquifer is maintained by recharge from the unconfined pumice aquifer following flow pathways beneath ephemeral stream valleys. The fen is developed on a down-thrown block of welded tuff and pre-eruption diatomaceous silt. Water levels in the fen are sensitive to inter-annual variations in precipitation. Low discharge, low temperature (5.0˚C to 6.5˚C), and low conductivity (30 to 50 μS/cm) springs appear to be fracture controlled and rising through welded tuff. Spring discharge and seepage through pumice from the welded tuff support perennial flow in the creek that also carries discharge from the seasonally flooded meadow when water levels are high enough to cross the knickpoint.