Oxidative addition of Fe(C0I4PR2H to Pt(C2H4)(PRf3)2 gives an equilibrium mixture of (OC)3Fe(p-PR2)(p-H)Pt(PRf3)2 and (OC),(H)Fe=t(PR' ,),, the first system in which an equilibration between bridge and terminal hydride bonding modes can be observed.
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