Strontium titanate SrTiO 3 (100), (110), and (111) single crystals, undoped or donor doped with up to 1 at% La, were isothermally equilibrated at temperatures between 1523 and 1773 K in synthetic air followed by two different methods of Sr tracer deposition: ion implantation of 87 Sr and chemical solution deposition of a thin 86 SrTiO 3 layer. Subsequently, the samples were diffusion annealed under the same conditions as before. The initial and final depth profiles were measured by SIMS. For strong La-doping both tracer deposition methods yield similar Sr diffusion coefficients, whereas for weak doping the tracer seems to be immobile in the case of ion implantation. The Sr diffusivity does not depend on the crystal orientation, but shows strong dependency on the dopant concentration supporting the defect chemical model that under oxidizing conditions the donor is compensated by Sr vacancies. A comparison with literature data on Sr vacancy, Ti, and La diffusion in this system confirms the concept that all cations move via Sr vacancies. Cation diffusion is several orders of magnitude slower than oxygen diffusion.

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Measurements of the temperature dependence of surface acoustic wave velocity were performed for propagation on X, Y, A C, AT, and along the x axis of several other rotated Y cuts of quartz over the temperature range -25° to +75°C. A pulsed rf technique was employed. To facilitate the measurement of angular dependence of the temperature coefficient of velocity, surface wave delay lines were constructed in which the waves were excited on the quartz by means of an interdigital electrode structure on a glass substrate which was brought into contact with the quartz. Calculations of the temperature coefficients of velocity and delay time were performed using an iterative computer program based on the work of Coquin and Tiersten. The measurements and calculations are in good agreement in most cases, the largest discrepancy being approximately five percent. It is concluded that the orientation which best combines lowtemperature dependence of delay time, high coupling constant, and a minimum of deleterious side effects is 42!0 rotated V-cut quartz with propagation along the x axis.

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