We report large and nonmonotonic dependences of the electro-optic (EO) coefficient r22 and the corresponding dielectric permittivity in pure LiNbO3 on the concentration of intrinsic defects related to the deviation from the stoichiometry of the crystal. This variation is caused mainly by the electro-mechanical contribution. A stoichiometric crystal possesses both large EO properties and resistance to optical damage which renders it much more suitable for use in laser Q-switching than the congruent crystal.
scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.