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New kinds of modiÐed electrodes have been prepared on the basis of electroactive polymers containing bimetallic " anil Ï and " salen Ï-type complexes. New tetrahydro " anil Ï ligands and complexes have been synthesized, giving birth to a new family of electroactive polymers. The polymers have been prepared potentiostatically and exhibit electrochemical properties analogous to simple polysalens. In the case of binuclear complexes both imino-and amino-linked monomers polymerize, but the polymers exhibit quite di †erent charge transfer dynamics.Electropolyme risation anodique de complexes binucle aires de type " anil Ï et " salen Ï et de leur de rive s tetrahydroge ne s. Un nouveau type dÏe lectrodes modiÐe es a e te e labore sur la base de polyme`res e lectroactifs issus de complexes bime talliques de type " anil Ï et " salen Ï. Nous avons synthe tise des ligands et complexes tetrahydro " anil Ï originaux donnant acce`s a`une nouvelle famille de polyme`res e lectroactifs. Les complexes binucle aires posse dant des liaisons imine et amine polyme risent e galement, mais les polyme`res pre sentent des comportements tre`s di †e rents sur le plan du transfert e lectronique.