ElEtrocromatografia capilar: contExtualização, Estado da artE E pErspEctivas milena pinotti segato, césar ricardo silva e isabel cristina sales fontes Jardim* Instituto de Química, Universidade Estadual de Campinas, CP 6154, 13084-971 Campinas -SP, BrasilRecebido em 25/3/08; aceito em 21/8/08; publiado na web em 26/1/09 CAPILLARY ELECTROCHROMATOGRAPHY: CONTEXTUALIZATION, STATE-OF-THE-ART AND PERSPECTIVES. Capillary electrochromatography (CEC) is a separation technique in which the mobile phase flow is based on the application of a voltage across a packed capillary, which generates an electroosmotic flow that transports the analytes along the capillary toward the detector. As it combines the separation mechanisms of high-performance liquid chromatography (HPLC) and of capillary electrophoresis (CE), CEC can be considered a hybrid of HPLC and CE. This review presents some fundamental aspects of CEC and is focused on the instrumental advances of the technique, such as column technology, operation modes and detection systems, presenting recent papers on these topics and some applications and perspectives about CEC.
Primeiramente, a Deus. Ao Prof. Dr. Gilberto Chierice pela disponibilidade do laboratório e pela receptividade. Ao Luiz, tio Lu, pela paciência e ajuda no laboratório sempre que precisei, e não foi pouco. À Dr a. Carla pela ajuda, amizade e consideração. Ao Prof. Dr. Massao Ionashiro pela colaboração, principalmente com os RMN's. Ao Prof. Dr. Alan Riga pelas rápidas, porém muito importantes discussões.
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