Al igand-promoted Rh III -catalyzed C(sp 2 ) À Ha ctivation/thiolation of benzamides has been developed. Using bidentate mono-N-protected amino acid ligands led to the first example of Rh III -catalyzed aryl thiolation reactions directed by weakly coordinating directing amide groups.T he reaction tolerates abroad range of amides and disulfide reagents.
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