The addition of transition element oxides to tungsten heavy alloys (WHAs) fabricated by powder metallurgy technique provides new materials with higher density and electrical conductivity, which may be adequate in some applications such as kinetic energy penetrators. Additionally, materials with higher electrical conductivity are required for electrical contact applications such as electrical discharge machining (EDM) electrode materials. WHAs were fabricated by compacting its mixed constituents followed by sintering. Ni, Co and Fe are used as binding phases of the tungsten particles and oxides of Zr, Ti and Y are used as oxide dispersing strengthening (ODS) agents of the sintered materials. The results show that all of the chosen factors (i.e., pressure of compaction process, temperature of sintering, type of binding material and type of oxide) have clear effects on all properties of ODS tungsten heavy alloy specimens. The density and electrical conductivity increase with the increase in sintering temperature. Hardness and compression strength were also measured to evaluate the mechanical properties of sintered samples.
Electron impact excitation rate coefficients, level population densities, and gain coefficients for six excited ions with Z = 51, 52, 53, 54, 55, 56 in the copper isoelectronic sequence have been calculated. The electron collisional excitation rate coefficients are calculated according to the analytical formulas of Vriens and Smeets. Fine structure energy levels, transition probabilities, and oscillator strengths needed in the calculations have been calculated using Cowan atomic structure code with relativistic corrections for [Ar]3d10nl with n = 4–7 and l = 0–6. The level population densities are calculated by solving the coupled rate equations involving 30 levels. Positive gain coefficients of the possible emitted lines are obtained at three selected electron temperatures, namely 1/4, 1/2, and 3/4 of the ionization energy. The present calculated data show promising values for the production of soft X-ray and XUV laser by collisional pumping for the transitions 5p–5s and 6d–5f with wavelengths between 108 and 571 Å. The values of the maximum gain coefficient are found to increase with atomic number and their order of magnitude ranges from102 to 104 cm−1.
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